Monday, 14 March 2011

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Transactions: INTERNATIONAL JOURNAL of ENERGY and ENVIRONMENT
Transactions ID Number: 20-551
Full Name: Shurong Wang
Position: Professor
Age: ON
Sex: Male
Address: State Key Laboratory of Clean Energy Utilization,Zhejiang University,Hangzhou
Country: CHINA
Tel: +86 571 87952801
Tel prefix:
Fax: +86 571 87951616
E-mail address: srwang@zju.edu.cn
Other E-mails: guoxiujuan@zju.edu.cn
Title of the Paper: catalytic pyrolysis of xylan-based hemicellulose over zeolites
Authors as they appear in the Paper: Xiujuan Guo, Shurong Wang, Yan Zhou, Zhongyang Luo
Email addresses of all the authors: guoxiujuan@zju.edu.cn,srwang@zju.edu.cn,weihaiyisu1987@163.com,cfb@zju.edu.cn
Number of paper pages: 8
Abstract: Xylan, poly (¦Â-D-xylopyranose [1¡ú4]) extracted from the beechwood, was selected as the model compound of hemicellulose to investigate its thermal behavior over zeolites by using the thermogravimetric analyzer coupled with Fourier transform infrared spectrometer (TG-FTIR), and an analytical pyrolyzer coupled with gas chromatography and mass spectrometer (Py-GC/MS). The chemical structure of xylan and characterization of catalysts were first studied. All the three catalysts, HZSM-5, H-¦Â and USY, had obvious influence on deoxygenation and fragmentation reactions during xylan pyrolysis. The dehydration in the initial stage was enhanced and the char formation was suppressed. USY had the best effect on dehydration with the consumption of oxygenated compounds, such as acids and furans. The presence of HZSM-5 and H-¦Â catalyzed the formation of water, CO2 and alkanes, with the degradation of char residues.
Keywords: Catalytic pyrolysis,Xylan,Hemicellulsoe,Zeolites,TG-FTIR
EXTENSION of the file: .doc
Special (Invited) Session: Catalytic pyrolysis of xylan-based hemicellulose over zeolites
Organizer of the Session: 650-310
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